From Silicon Labs:
Band Edge Concerns: The top end of the 802.15.4 channel band (Channel 26 and occasionally Channels 24 an 25 at very high output powers) usually pushes up against the limits of the band, encroaching into the reserved area in the adjacent (higher) frequencies. Therefore, it's often necessary to artificially limit (with software) output power on these upper channels (as much as -9 or -10 dBm) in order to pass FCC TX testing.
I read somewhere (sorry I don't have the source) some device manufacturers completely omit 26 to avoid possible interference.
