Posting this in the lounge, because I don't really expect any answers to what happened last night, but will throw it out there anyhow.
Of course this happens right after I armed the alarm and was ready to go to bed. All of a sudden, it's like my system had eaten some bad sushi and expelled it all over the zigbee network, tuning my house into an 80's disco, The led bars on many of my Inovelli 2-1 switches started turning on and off with random colors, and some of my hue downlights went to 100% while others flashed on and off. This went on for a few minutes.
I doubt it had anything to do with arming the alarm system, as that happened at 11;44 pm and there are no unusual log entries around that event. But a few minutes later, as I'm trying to figure out why some of my hue downlights are burning our retinas, I see this:
What the hell? All of these are Hue bulbs or downlights, all connected to HE (I don't have a Hue hub). There are no rules, switches or anything else that command every last Hue device at the same time, and no automations that fire off at that time of night.
Wifi is on channels 1 and 6 and my UDM Pro-SE reports no interference for the past week:

Every last light and fan switch (50+) in the house is an Inovelli 2-1 so I believe I have a solid mesh. How could I not; there are multiple mains-powered devices in literally every room. Hub is a C8-Pro using the supplied power adapter, zigbee on channel 20 at power level 8. The vast majority of devices in the house are new, zigbee 3.0 devices (50+ Inovellis, 10 Hue bulbs, 23 Hue downlight retrofits). Only a few battery- powered temp/humidity sensors, and a few plug-in switches and dimmers.
Things work correctly about 90% of the time, but there's always something that doesn't turn on or off or work as it should. Was the same on the C7, upgrading to C8-Pro didn't change anything. I am really regretting switching to zigbee for most of my devices in this house. In my old house, most everything was z-wave and everything was rock-solid.

