I know English is not your first language, but your responses come off a bit rude. I'm only trying to offer suggestions to help. That's all I want to do for anyone here. Sorry if you took my ribbing as an attack on you. Not at all the intention.
I don't see how your stating that your batteries are 14 months old and then my repeating those exact words here are an assumption of anything. You are using a method that isn't even recommended by even the author of the driver to test accurate battery levels. Your reading of 2.64v is low and likely to causing the issue. Likely, does not mean absolutely is.
My writing I'm "fairly certain" about something, means I'm not 100% certain. So you can ease up a bit and not cast aspersions on people. I never wrote that I was certain. I wrote fairly certain. It means one is almost certain, but does have some doubt. That doubt could possibly be proven true or false by actually removing the battery, putting in a proper battery tester and finding out if it's indeed weak. I'm guessing it is too weak for proper performance. Most people's experience, my own included, with not only Xiaomi but also other Zigbee devices is that they do not perform properly when the batteries are low. Low is going to be subjective, based on the device, not one's interpretation of what an acceptable battery level is. They're all going to act differently at different minimum battery levels. I don't know what the level is that's acceptable for Xiaomi or any other for that matter, but personally if I have trouble with a device, replacing the battery is the very first thing I'm going to do. Even if I measure it with a battery tester, I would still replace it. A measured value in most battery testers is completely different than a measured value under load. So I'm not claiming that's a perfect guide and the absolute definitive solution. The ZTS testers I believe do put the battery under load to test, but that's neither here, nor there.
To me, and this is just my opinion, I'm not claiming it is fact, but rather a guess based on experience, that the low battery level is almost certainly the cause of any Zigbee device misbehaving. Don't believe me? I don't need you to. Ask around. But please don't tell me that you don't need to change batteries, can't figure out why your devices are quickly dropping off the network and that obviously it's something wrong with the Hubitat Zigbee implementation. No sale here sir!