It was Active as far as I can tell from what you've shown. Your logs are inscrutable, but don't show anything to illuminate its state prior to 6:00 AM. The one highlighted log entry reveals nothing. How about the Activator Device state? Look at its Events logs. The Active state of the app is tied to the Activator when you have Indicator in use. And, only if the app is Active does mode adjust do anything.
However, that bug you pointed out before about line 2203 throwing an error is messing up the Active state being set correctly by the indicator. So, until that fix is released, my guess is that indicator is not setting the app state, so it's remaining Active. Try a test: Open the app, if it shows Active at the top, hit Turn Off in the ui. Then change the mode and see if it does anything.