Now start moving the devices themselves.
Start with the closest Zigbee device. Put the hub into pairing then do the pairing dance with the device. The hub will tell you it found a previously paired device and just drop it right in to all your automations. Repeat.
When your success at Zigbee allows you to feel confident, it's time to try a ZWave device. They do NOT come across as easily.
There's a technique that involves changing the DNI of a device in the Hub then Joining a ZWave device. It will get a brand new DNI and you can change it to be the old DNI.