You're welcome. And yes, you can have a rule that will turn up the temp on the thermostat, as a response to the radiator valve being adjusted. I'd include lgoic that if the TRV temperature isn't hit after a certain time period, that the override would stop and return the thermostat to previous temp(which gets stored in a variable) I'm not the most skilled at logic, but there are plenty here who can help with the logic, and variables, to make it all run smoothly.
In the thread below are folks using TRV's with webcore, but with the latest rule machine, you don't need webcore.
@mark.cockcroft seems to be in pretty deep with TRV's and automations